Study of Adsorption Kinetics of Fe Metal in Batik Cual Waste using Chitosan of Rice Crab Shells

Penulis

  • Fadillah Ramadhani Department of Physics, Universitas Bangka Belitung, Bangka 33172 Indonesia
  • Widodo Budi Kurniawan Department of Physics, Universitas Bangka Belitung, Bangka 33172 Indonesia
  • Widodo Budi Kurniawan Aldila Department of Physics, Universitas Bangka Belitung, Bangka 33172 Indonesia

DOI:

https://doi.org/10.11594/timeinphys.2023.v1i2p93-100

Kata Kunci:

adsorbent, batik cual waste, adsorption kinetic, Fe

Abstrak

Fe metal is one of the heavy metal composition contained in cual batik waste. The content of these metal has potency as pollutan and can increase the risk of chemical substance stored in various aquatic biota and very dangerous for human consumption because it is toxic in the long term. In this research, batik waste treatment has been carried out by decadarizing Fe metal using adsorbent agent based from citosan. Paddy crab shell was extracted through demineralization, deproteination, decolorization, and deacetylation to become chitosan powder. Chitosan powder becomes an adsorbent in the adsorption process with adsorption data collection patterns for various contact times of 30, 60, 90, 120, 150, 180, 210, and 240 minutes. The adsorption results were kinetic modeled using the kinetic model of first order, second order, and BMG. From that three models obtained the R2 value that is closest to 1 is the BMG kinetic model, which is 0.999602. In addition, this model has the advantage that is it can find out the magnitude of the decolorization decay constant and the rate of decolorization of Fe metal.

Referensi

Al Ayyubi, M.S., Farikhah & Safitri, N.M., 2022. The Effect of Chitosan Extracted from Green Mussel Shells Perna viridison Sonneratia caseolaris Mangrove Syrup Preservation. Jurnal Biologi Tropis, 22(1), pp.251-64.

Aldila, H., Dalimunthe, D.Y. & Nuryadin, A., 2020. Ekstraksi Kitosan dari Limbah Cangkang Udang sebagai Adsorben Ion Logam Cu pada Air Pasca Tambang Timah. PROMINE, 8(2), pp.65-71.

Behnajady, M.A., Modirshahla, N. & Ghanbary, F., 2007. A Kinetic Model for the Decolorization of C.I. Acid Yellow 23 by Fenton Process. Journal of Hazardous Materials, 148, pp.98-102.

Dalimunthe, D.Y., Indriawati, A., Hisyam, E.S. & Aldila, H., 2023. sotherm Studies of Cu (II) Adsorption in Kolong Bangka’s Water onto NaOH-Deacetylated Shrimp Shells Waste Chitin (Kajian Isoterm Adsorpsi Cu(II) dalam Air Kolong Bangka denganKitin Limbah Cangkang Udang Terdeasetilasi NaOH). Stannum : Jurnal Sains dan Terapan Kimia, 5(1), pp.1-7.

Darjito, D., Purwonugroho, D. & Ningsih, R.,2014. The Adsorption of Cr (VI) Using Chitosan-Alumina Adsorbent.The Journal of Pure and Applied Chemistry Research, 3, pp.53-61.

Hamdini, M., 2022. Kinetika Reaksi Dekolorisasi Limbah Cair Batik Cual Melalui Proses Oksidasi Maju Berbasis CuO. Skripsi. Bangka: Jurusan Fisika Universitas Bangka Belitung.

Ho, Y.S. & McKay, G., 1999. Pseudo-second Order Model for Sorption Processes. Pro. Biochem, 34, pp.451-65.

Kim, T. & Zoh, K.D., 2020. Removal Mechanism of Heavy Metal (Cu, Ni, Zn, and Cr) in the Presence of Cyanide During Electrokoagulation using Fe and Al elektrodes. Journal of Water Process Engineering, 33(1), pp.101-09.

Kumalasari, 2021. Pengaruh Fraksi Massa HAp Terhadap Nilai Kapasitansi Spesifik Komposit HAp/Kitosan/PVA Dari cangkang Kepiting Sawah. Skripsi. Bangka: Jurusan Fisika Universitas Bangka Belitung.

Livia, Kurniawan, W.B. & Aldila, H., 2022. Pengaruh variasi waktu kontak terhadap nilai efisiensi dan mekanisme kinetika adsorpsi logam besi (Fe) pada limbah batik cual menggunakan kitosan. Jurnal Riset Fisika Indonesia, 2(2), pp.31-36.

Mashuni, M. et al., 2021. Pemanfaatan Kitosan dari Cangkang Kepiting Bakau (Scylla serrata) dengan Metode Microwave sebagai Bahan Dasar Kapsul Obat. ALCHEMY Jurnal Penelitian Kimia, pp.74-82.

Saputra, A., Tiandho, Y. & Afriani, F., 2022. Studi Kinetika Pada Proses Elektrokoagulasi Zat Warna Metilen Biru. Jurnal Riset Fisika Indonesia, 3(1), pp.1-11.

Suprihatin, H., 2014. Kandungan Organik Limbah Cair Industri Batik Jetis Sidoarjo dan Alternatif Pengolahannya. Riau: Pusat Penelitian Lingkungan Hidup Universitas Riau.

Thiandho, Y. et al., 2018. Utilization of Wasted Cockle Shell as a Natural Coagulant and a Neutralizer of Polluted Water in Bangka Blitung Islands, Indonesia. Journal of Physics : Conference Series, 1013(1), pp.1-5.

Tiandho, Y. et al., 2018. Accurate model for temperature dependence of solar cell performance according to phonon energy. Latvian Journal of Physics and Technical Sciences, 55(5), pp.15-25.

Utami, D.D., Widodo, E. & Sjofjan, O., 2013. Pengaruh Penggunaan Tepung Kepiting Sawah (Parathelphusa maculata) dalam Pakan Terhadap Kualitas Karkas Ayam Pedaging. pp.1-7.

Zhang, G. et al., 2020. Efficient removal of Cu (ii), Zn (ii), and Cd(ii) from Aqueous Solution by a Mineral-Rich Biochar Derived from a Spent Mushroom (Agaricus bisporus). Substrate. Material, 14, pp.1-17.

Diterbitkan

2023-08-21

Cara Mengutip

Fadillah Ramadhani, Widodo Budi Kurniawan, & Aldila, W. B. K. (2023). Study of Adsorption Kinetics of Fe Metal in Batik Cual Waste using Chitosan of Rice Crab Shells. TIME in Physics, 1(2), 93–100. https://doi.org/10.11594/timeinphys.2023.v1i2p93-100

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